International Chemical Safety Cards

o-CHLOROBENZALDEHYDE

ICSC: 0641

o-CHLOROBENZALDEHYDE
2-Chlorobenzaldehyde
C₇H₅ClO/ClC₆H₄CHO
Molecular mass: 140.6
CAS # 89-98-5
RTECS # CU5075000
ICSC # 0641
UN # 1760
EC # 605-011-00-X

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Powder, water spray, foam, carbon dioxide.
EXPLOSION			In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE		PREVENT GENERATION OF MISTS!
INHALATION	Burning sensation. Cough. Sore throat.	Ventilation.	Fresh air, rest. Refer for medical attention.
SKIN	MAY BE ABSORBED! Redness. Burning sensation. Pain.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
EYES	Redness. Pain.	Safety goggles or face shield.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION	Abdominal cramps. Burning sensation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent and remove to safe place.

Separated from food and feedstuffs. Dry. Well closed.

Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.
C symbol
R: 34
S: (1/2-)26-45
UN Hazard Class: 8

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0641

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

o-CHLOROBENZALDEHYDE

ICSC: 0641

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PHYSICAL STATE; APPEARANCE:
COLOURLESS TO YELLOW LIQUID , WITH PUNGENT ODOUR.

PHYSICAL DANGERS:

CHEMICAL DANGERS:
The substance decomposes on heating, producing toxic and corrosive fumes including hydrogen chloride (see ICSC # 0126).

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV not established.

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance severely irritates the eyes, the skin and the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point: 211.9°C
Melting point: 12.4°C
Relative density (water = 1): 1.25
Solubility in water: miscible

Vapour pressure, kPa at 25°C: 0.04
Flash point: 90°C c.c
Auto-ignition temperature: 385°C

ENVIRONMENTAL
DATA

The substance is toxic to aquatic organisms.

N O T E S

The apparent melting point caused by loss of crystal water is given. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.

Transport Emergency Card: TEC (R)-80G20b

IMPORTANT LEGAL NOTICE:

Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.