ETHYLAMINE

ICSC: 0153

ETHYLAMINE
Ethanamine
Aminoethane
(cylinder)
C₂H₅NH₂/C₂H₇N
Molecular mass: 45.1
CAS # 75-04-7
RTECS # KH2100000
ICSC # 0153
UN # 1036
EC # 612-002-00-4

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Extremely flammable. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames, NO sparks, and NO smoking.	Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out; in other cases extinguish with powder, carbon dioxide.
EXPLOSION	Gas/air mixtures are explosive.	Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding) if in liquid state.	In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.

EXPOSURE		STRICT HYGIENE!	IN ALL CASES CONSULT A DOCTOR!
INHALATION	Cough. Laboured breathing. Sore throat.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest. Refer for medical attention.
SKIN	MAY BE ABSORBED! Redness. Burning sensation.	Protective gloves. Protective clothing.	Refer for medical attention.
EYES	Redness. Pain.	Face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION	Abdominal pain. Burning sensation.	Do not eat, drink, or smoke during work. Wash hands before eating.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Evacuate danger area! Consult an expert! Ventilation. Remove all ignitions sources. NEVER direct water jet on liquid (extra personal protection: complete protective clothing including self-contained breathing apparatus).

Fireproof. Cool.

F symbol
Xi symbol
R: 12-36/37
S: (2-)16-26-29
UN Hazard Class: 2.1

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0153

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

ETHYLAMINE

ICSC: 0153

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PHYSICAL STATE; APPEARANCE:
COLOURLESS COMPRESSED LIQUEFIED GAS , WITH PUNGENT ODOUR.

PHYSICAL DANGERS:
The gas is heavier than air and may travel along the ground; distant ignition possible.

CHEMICAL DANGERS:
The substance decomposes on heating producing toxic gases including nitrogen oxides. The solution in water is a strong base, it reacts violently with acid and is corrosive. Reacts violently with acid, strong oxidants and organic compounds causing fire and explosion hazard. Attacks many non-ferrous metals and plastics.

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV: 5 ppm; 9.2 mg/m³ (as TWA) (ACGIH 1993-1994).
TLV (as STEL): 15 ppm; 27.6 mg/m³ (ACGIH 1993-1994).

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
A harmful concentration of this gas in the air will be reached very quickly on loss of containment.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance severely irritates the eyes, the skin and the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the kidneys and lungs , resulting in tissue lesions.

PHYSICAL
PROPERTIES

Boiling point: 17°C
Melting point: -81°C
Relative density (water = 1): 0.7
Solubility in water: miscible
Vapour pressure, kPa at 20°C: 121

Relative vapour density (air = 1): 1.55
Flash point: -17°C c.c.
Auto-ignition temperature: 380°C
Explosive limits, vol% in air: 3.5-14
Octanol/water partition coefficient as log Pow: -0.27/-0.08 (calculated)

ENVIRONMENTAL
DATA

This substance may be hazardous to the environment; special attention should be given to fish.

N O T E S

Ethylamine is also supplied commercially in the form of 70% aqueous solution (UN number: 2270). Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.

Transport Emergency Card: TEC (R)-20G12
NFPA Code: H 3; F 4; R 0;

ADDITIONAL INFORMATION

ICSC: 0153	ETHYLAMINE
© IPCS, CEC, 1993

IMPORTANT LEGAL NOTICE:

Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.