International Chemical Safety Cards

ETHANE IODIDE ICSC: 0479

ETHANE IODIDE
Iodoethane
Ethyl iodide
Monoiodoethane
C2H5I / CH3-CH2I
Molecular mass: 155.97
CAS # 75-03-6
RTECS # KI4750000
ICSC # 0479
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Flammable.
NO open flames, NO sparks, and NO smoking. NO contact with silver chlorite.
Powder, water spray, foam, carbon dioxide.
EXPLOSION Above 53°C explosive vapour/air mixtures may be formed.
Above 53°C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
 
EXPOSURE
PREVENT GENERATION OF MISTS!

INHALATION Unpleasant taste. Confusion. Cough. Drowsiness. Shortness of breath. Sore throat. Unconsciousness. Pain in the extremities.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention.
SKIN MAY BE ABSORBED! Redness. Pain (see Inhalation).
Protective gloves. Protective clothing.
Rinse and then wash skin with water and soap. Refer for medical attention. Wear protective gloves when administering first aid.
EYES VAPOUR WILL BE ABSORBED! Redness. Pain.
Safety goggles, face shield, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION Abdominal cramps (see Inhalation).
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Collect leaking liquid in covered labelled containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place (extra personal protection: A/P2 filter respirator for organic vapour and harmful dust).
Fireproof. Separated from strong oxidants.

SEE IMPORTANT INFORMATION ON BACK
ICSC: 0479 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

ETHANE IODIDE ICSC: 0479

I

M

P

O

R

T

A

N

T



D

A

T

A
PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. TURNS DARK ON EXPOSURE TO LIGHT.

PHYSICAL DANGERS:
The vapour is heavier than air.

CHEMICAL DANGERS:
The substance decomposes on burning producing iodine and hydrogen iodide. Reacts with oxidants. Reacts violently with silver chlorite. causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and through the skin.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the nervous system, kidneys, thyroid and liver.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
 Boiling point: 72°C
Melting point: -108°C
Relative density (water = 1): 1.9358
Solubility in water, g/100 ml at 20°C: 0.4
Vapour pressure, kPa at 25°C: 18.3		 Relative vapour density (air = 1): 5.4 calculated
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.8
Flash point: 53°C c.c.
Octanol/water partition coefficient as log Pow: 2.0
ENVIRONMENTAL
DATA
N O T E S
Explosive limits are unknown in literature, although the substance is combustible and has a flash point <61°C. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. No odour warning if toxic concentrations are present.
ADDITIONAL INFORMATION


ICSC: 0479 ETHANE IODIDE
© IPCS, CEC, 1993
IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.