PROPYNE

ICSC: 0560

PROPYNE
Allylene
Methyl acetylene
(cylinder)
C₃H₄ / CH₃-C=CH
Molecular mass: 40.07
CAS # 74-99-7
RTECS # UK4250000
ICSC # 0560
UN # 1954

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Extremely flammable.	NO open flames, NO sparks, and NO smoking.	Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out; in other cases extinguish with water spray.
EXPLOSION	Gas/air mixtures are explosive.	Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding) if in liquid state. Use non-sparking handtools. Prevent build-up of electrostatic charges (e.g., by grounding).	In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.

EXPOSURE
INHALATION	Dizziness. Headache. Nausea. Unconsciousness.	Local exhaust or breathing protection.	Fresh air, rest. Artificial respiration if indicated. Refer for medical attention. See Notes.
SKIN	ON CONTACT WITH LIQUID: FROSTBITE.	Cold-insulating gloves.	ON FROSTBITE: rinse with plenty of water, do NOT remove clothes.
EYES		Face shield.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Evacuate danger area! Ventilation. Remove all ignition sources. NEVER direct water jet on liquid (extra personal protection: chemical protection suit including self-contained breathing apparatus).

Fireproof. Cool.

UN Hazard Class: 2.1

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0560

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

PROPYNE

ICSC: 0560

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PHYSICAL STATE; APPEARANCE:
COLOURLESS COMPRESSED GAS , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:
The gas is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated.

CHEMICAL DANGERS:
The substance decomposes on heating and increasing pressure , causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV: 1000 ppm; 1640 mg/m³ (ACGIH 1996).

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation.

INHALATION RISK:
On loss of containment this gas can cause suffocation by lowering the oxygen content of the air in confined areas.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the respiratory tract. Rapid evaporation of the liquid may cause frostbite. Exposure could cause lowering of consciousness.

PHYSICAL
PROPERTIES

Boiling point: -23.2°C
Melting point: -102.7°C
Relative density (water = 1): 0.70
Solubility in water, g/100 ml: 0.36

Vapour pressure, kPa at 20°C: 521
Relative vapour density (air = 1): 1.4
Flash point: Flammable Gas
Explosive limits, vol% in air: 2.4-11.7

ENVIRONMENTAL
DATA

N O T E S

High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death. Check oxygen content before entering area. After use for welding, turn valve off; regularly check tubing, etc., and test for leaks with soap and water. The measures mentioned in section PREVENTION are applicable to production, filling of cylinders, and storage of the gas.

Transport Emergency Card: TEC (R)-20G41
NFPA Code: H2; F4; R2;

ADDITIONAL INFORMATION

ICSC: 0560	PROPYNE
© IPCS, CEC, 1993

IMPORTANT LEGAL NOTICE:

Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.