International Chemical Safety Cards

AMITROLE ICSC: 0631
AMITROLE
1,2,4-Triazol-3-ylamine
3-Amino-1H-1,2,4-triazole
Aminotriazole
C2H4N4
Molecular mass: 84.1
CAS # 61-82-5
RTECS # XZ3850000
ICSC # 0631
UN # 2588
EC # 613-011-00-6
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


 
EXPOSURE
STRICT HYGIENE!

INHALATION
Ventilation (not if powder), local exhaust, or breathing protection.
Refer for medical attention.
SKIN
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
EYES
Face shield or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Do NOT wash away into sewer. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: P3 filter respirator for toxic particles).
Separated from food and feedstuffs, incompatible substances (see Chemical Dangers). Keep in the dark. Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
Xn symbol
R: 40-48/22
S: (2-)36-37
UN Hazard Class: 6.1
UN Packing Group: III
Severe marine pollutant.
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0631 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

AMITROLE ICSC: 0631

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PHYSICAL STATE; APPEARANCE:
ODOURLESS, COLOURLESS CRYSTALS.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating producing toxic fumes of nitrogen oxides. The substance is a weak base. Reacts with strong acids, strong oxidants, acid chlorides and acid anhydrides. Attacks iron, copper and aluminium.

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV: ppm; 0.2 mg/m3 (as TWA) (ACGIH 1993-1994).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the thyroid.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the thyroid , resulting in goitrogenic effects.
PHYSICAL
PROPERTIES
 Melting point: 159°C
Solubility in water: good
Octanol/water partition coefficient as log Pow: -0.65
ENVIRONMENTAL
DATA
 This substance may be hazardous to the environment; special attention should be given to plants.
N O T E S
Temperature of decomposition unknown in literature. Depending on the degree of exposure, periodic medical examination is indicated.
ADDITIONAL INFORMATION


ICSC: 0631 AMITROLE
© IPCS, CEC, 1993
IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.