International Chemical Safety Cards

EPN ICSC: 0753
EPN
O-Ethyl O-4-nitrophenyl phenyl phosphonothioate
C14H14NO4PS
Molecular mass: 323.3
CAS # 2104-64-5
RTECS # TB1925000
ICSC # 0753
UN # 2783
EC # 015-036-00-2
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Foam, powder, carbon dioxide.
EXPLOSION The explosion hazard will depend on the solvent used in the formulation or on the characteristics of the dust.


 
EXPOSURE
STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
IN ALL CASES CONSULT A DOCTOR!
INHALATION Convulsions. Dizziness. Laboured breathing. Nausea. Unconsciousness. Vomiting. Pupillary constriction, muscle cramp, excessive salivation.
Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
SKIN MAY BE ABSORBED! (Further see Inhalation).
Protective gloves. Protective clothing.
Rinse and then wash skin with water and soap. Refer for medical attention.
EYES
Face shield, or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION Abdominal cramps. Diarrhoea. Laboured breathing. Nausea. Unconsciousness. Vomiting. Pupillary constriction, muscle cramps, excessive salivation.
Do not eat, drink, or smoke during work.
Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Do NOT wash away into sewer. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (extra personal protection: complete protective clothing including self-contained breathing apparatus).
Separated from food and feedstuffs. Dry.
Do not transport with food and feedstuffs.
T symbol
R: 26/27/28
S: 1-13-28-45
UN Hazard Class: 6.1
UN Packing Group: I
Severe marine pollutant.
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0753 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

EPN ICSC: 0753

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PHYSICAL STATE; APPEARANCE:
YELLOW TO BROWN CRYSTALLINE POWDER , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating and on burning producing toxic and corrosive fumes including nitrogen oxides, phosphorous oxides, sulfur oxides. The substance decomposes under influence of alkalies (hydrolysis).

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV: ppm; 0.5 mg/m3 (skin) (ACGIH 1991-1992).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin, by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the nervous system , resulting in convulsions, respiratory failure. Cholinesterase inhibitor. Exposure at high level may result in death. The effects may be delayed. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Cholinesterase inhibitor; cumulative effect is possible: see acute hazards/symptoms.
PHYSICAL
PROPERTIES
 Melting point: 36°C
Relative density (water = 1): 1.27 at 25°C		 Solubility in water: none
Vapour pressure, Pa at 25°C:
ENVIRONMENTAL
DATA
 This substance may be hazardous to the environment; special attention should be given to bees and fish.
NOTES
Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of acute intoxication do not become manifest until 30 minutes to 1-2 hours. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home.
Transport Emergency Card: TEC (R)-61 G40
ADDITIONAL INFORMATION


ICSC: 0753 EPN
© IPCS, CEC, 1993
IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.