International Chemical Safety Cards ALLYLAMINE ICSC: 0823 ALLYLAMINE 2-Propen-1-amine 3-Aminopropylene 2-Propenylamine C3H7N/CH2=CHCH2NH2 Molecular mass: 57.1 CAS # 107-11-9 RTECS # BA5425000 ICSC # 0823 UN # 2334 EC # 612-046-00-4 TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames, NO sparks, and NO smoking. AFFF. Alcohol-resistant foam. Powder. Carbon dioxide. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. In case of fire: keep drums, etc., cool by spraying with water.   EXPOSURE STRICT HYGIENE! INHALATION Burning sensation. Cough. Chest pain. Shortness of breath. Sore throat. Ventilation, local exhaust, or breathing protection. Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention. SKIN MAY BE ABSORBED! Redness. Pain. Blisters. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention. EYES Severe eye irritation. Redness. Pain. Tear drawing. Blurred vision. Loss of vision. Face shield or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. INGESTION Burning sensation. Headache. Nausea. Weakness. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Evacuate danger area! Consult an expert! Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place (extra personal protection: complete protective clothing including self-contained breathing apparatus). Fireproof. Separated from strong oxidants, strong acids, combustible materials, food and feedstuffs. Cool. Dry. Keep tightly closed. Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs. F symbol T symbol R: 11-23/24/25 S: 9-16-24/25-44 UN Hazard Class: 6.1 UN Subsidiary Risks: 3 UN Packing Group: I SEE IMPORTANT INFORMATION ON BACK ICSC: 0823 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards ALLYLAMINE ICSC: 0823 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS TO LIGHT YELLOW LIQUID , WITH PUNGENT ODOUR. PHYSICAL DANGERS: The vapour is heavier than air and may travel along the ground; distant ignition possible. CHEMICAL DANGERS: The substance decomposes on heating and on burning producing toxic fumes (nitrogen oxides). Reacts violently with oxidants causing explosion hazard. Reacts violently with acids and acid anhydrides. Corrosive to copper (alloys), aluminium, zinc (alloys) and steel. OCCUPATIONAL EXPOSURE LIMITS (OELs): TLV not established. PDK: 0.5 mg/m3 P (USSR 1987). ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. INHALATION RISK: A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: Corrosive. The substance is very corrosive to the eyes, the skin and the respiratory tract. Inhalation of the vapour may cause lung oedema (see Notes). Inhalation of the vapour may cause effects on the heart. Exposure may result in death. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact may cause skin sensitization. PHYSICAL PROPERTIES Boiling point: 55-58°C Melting point: -88°C Relative density (water = 1): 0.76 Solubility in water: miscible Vapour pressure, kPa at 20°C: 26.4 Relative vapour density (air = 1): 2.0 Flash point: -29°C Auto-ignition temperature: 370°C Explosive limits, vol% in air: 2.2-22

ENVIRONMENTAL DATA
NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered. Transport Emergency Card: TEC (R)-165 NFPA Code: H 3; F 3; R 1;

ADDITIONAL INFORMATION
ICSC: 0823 ALLYLAMINE © IPCS, CEC, 1993

IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.