International Chemical Safety Cards

p-CRESOL ICSC: 0031
p-CRESOL
4-Hydroxy-1-methylbenzene
4-Methylphenol
Para-hydroxytoluene
C7H8O/CH3C6H4OH
Molecular mass: 108.2
CAS # 106-44-5
RTECS # GO6475000
ICSC # 0031
UN # 2076
EC # 604-004-00-9
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible.
NO open flames.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Above 86°C explosive vapour/air mixtures may be formed.
Above 86°C use a closed system, ventilation.

 
EXPOSURE
STRICT HYGIENE!
IN ALL CASES CONSULT A DOCTOR!
INHALATION Burning sensation. Cough. Headache. Laboured breathing. Nausea. Vomiting.
Local exhaust or breathing protection.
Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention.
SKIN MAY BE ABSORBED! Redness. Pain. Blisters.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
EYES Redness. Pain. Severe deep burns.
Face shield or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION Abdominal cramps. Burning sensation. Collapse.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: complete protective clothing including self-contained breathing apparatus).
Separated from strong oxidants, food and feedstuffs.
Do not transport with food and feedstuffs.
T symbol
R: 24/25-34
S: (1/2-)36/37/39-45
Note: C
UN Hazard Class: 6.1
UN Subsidiary Risks: 8
UN Packing Group: II
Marine pollutant.
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0031 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

p-CRESOL ICSC: 0031

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PHYSICAL STATE; APPEARANCE:
COLOURLESS CRYSTALS , WITH CHARACTERISTIC ODOUR. TURNS DARK ON EXPOSURE TO AIR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
Reacts violently with strong oxidizing agents, causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV: 5 ppm; 22 mg/m3 (as TWA) (skin) (ACGIH 1993-1994).
MAK: 5 ppm; 22 mg/m3; skin (1992).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
Corrosive. The substance is corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion as well. Inhalation of vapour or aerosol may cause lung oedema (see Notes). The substance may cause effects on the central nervous system and various organs.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis.
PHYSICAL
PROPERTIES
 Boiling point: 202°C
Melting point: 35°C
Relative density (water = 1): 1.02
Solubility in water, g/100 ml at 25°C: 1.9
Vapour pressure, Pa at 25°C: 15		 Relative vapour density (air = 1): 3.7
Flash point: 86°C c.c.
Auto-ignition temperature: 559°C
Explosive limits, vol% in air: 1.0-?
Octanol/water partition coefficient as log Pow: 1.94
ENVIRONMENTAL
DATA
 This substance may be hazardous to the environment; special attention should be given to water. It is strongly advised not to let the chemical enter into the environment because it persists in the environment.
N O T E S
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
Transport Emergency Card: TEC (R)-37A
NFPA Code: H 3; F 2; R 0;
ADDITIONAL INFORMATION


ICSC: 0031 p-CRESOL
© IPCS, CEC, 1993
IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.