International Chemical Safety Cards p-BROMOANILINE ICSC 1226 p-BROMOANILINE 4-Bromobenzenamine p-Bromophenylamine C6H6BrN/BrC6H4NH2 Molecular mass: 172.04 CAS # 106-40-1 RTECS # BW9280000 ICSC # 1226 TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION   EXPOSURE STRICT HYGIENE! INHALATION Blue lips or finger nails. Blue skin. Dizziness. Headache. Local exhaust or breathing protection. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention. SKIN Blue lips or fingernails. Blue skin (further see Inhalation). Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. EYES Safety spectacles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. INGESTION Blue lips or fingernails. Blue skin. Dizziness. Headache. Laboured breathing. Do not eat, drink, or smoke during work. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into clean containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: P2 filter respirator for harmful particles). Separated from strong oxidants, acids. Well closed. SEE IMPORTANT INFORMATION ON BACK ICSC 1226 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards p-BROMOANILINE ICSC 1226 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS TO WHITE RHOMBIC CRYSTALS , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating or on burning producing toxic and corrosive fumes including hydrogen bromide and nitrogen oxides (see ICSC # 0282). The substance is a weak base. Reacts with acids. OCCUPATIONAL EXPOSURE LIMITS (OELs): TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the blood , resulting in formation of methaemoglobin. The effects may be delayed. Medical observation is indicated. PHYSICAL PROPERTIES Boiling point (decomposes): 230-250°C Melting point: 66-66.5°C Relative density (water = 1): See Notes Solubility in water: none Vapour pressure, Pa at 25°C: 22.6 Relative vapour density (air = 1): 5.9 Octanol/water partition coefficient as log Pow: 2.26

ENVIRONMENTAL DATA
N O T E S
Density of the liquid at 100°C is 1.4970. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. NFPA Code: H2; F1; R0;

ADDITIONAL INFORMATION
ICSC 1226 p-BROMOANILINE © IPCS, CEC, 1993

IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.