International Chemical Safety Cards

p-NITROTOLUENE

ICSC: 0932

p-NITROTOLUENE
4-Nitrotoluene
1-Methyl-4-nitrobenzene
p-Methylnitrobenzene
C₇H₇NO₂/C₆H₄(CH₃)NO₂
Molecular mass: 137.1
CAS # 99-99-0
RTECS # XT3325000
ICSC # 0932
UN # 1664
EC # 609-006-00-3

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Combustible. Many reactions may cause fire or explosion.	NO open flames.	Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION			In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE		PREVENT DISPERSION OF DUST! STRICT HYGIENE!
INHALATION	Blue lips or finger nails. Blue skin. Cough. Dizziness. Headache. Laboured breathing. Sore throat.	Local exhaust or breathing protection.	Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
SKIN	MAY BE ABSORBED! Redness. Pain (further see Inhalation).	Protective gloves. Protective clothing.	Rinse and then wash skin with water and soap. Refer for medical attention. Wear protective gloves when administering first aid.
EYES	Redness. Pain.	Safety goggles, face shield, or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
INGESTION	Abdominal pain. Blue lips or fingernails. Blue skin. Dizziness. Headache. Laboured breathing. Sore throat. Unconsciousness.	Do not eat, drink, or smoke during work.	Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Do NOT wash away into sewer. Sweep spilled substance into containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment (extra personal protection: self-contained breathing apparatus).

Separated from combustible and reducing substances, strong oxidants, strong bases, strong acids, food and feedstuffs. Tightly closed. Cool. Dry. Keep in a well-ventilated room.

Do not transport with food and feedstuffs.
T symbol
R: 23/24/25-33
S: 28-37-44
UN Hazard Class: 6.1
UN Packing Group: II

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0932

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards

p-NITROTOLUENE

ICSC: 0932

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PHYSICAL STATE; APPEARANCE:
YELLOW CRYSTALS , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:

CHEMICAL DANGERS:
The substance decomposes on heating producing toxic fumes (nitrogen oxides). Reacts violently with strong oxidizers or sulfuric acid causing fire and explosion hazard. Attacks some forms of plastics, rubber and coatings.

OCCUPATIONAL EXPOSURE LIMITS (OELs):
TLV (as TWA): 2 ppm; 11 mg/m³ (skin) (ACGIH 1991-1992).

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes, the skin, and the respiratory tract. The substance may cause effects on the blood , resulting in formation of methaemoglobin. Exposure may result in death. The effects may be delayed (see Notes). Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the liver and kidney , resulting in injury.

PHYSICAL
PROPERTIES

Boiling point: 238°C
Melting point: 53-54°C
Relative density (water = 1): 1.29
Solubility in water: none

Vapour pressure, kPa at 65°C: 0.173
Relative vapour density (air = 1): 4.72
Flash point: 106°C
Octanol/water partition coefficient as log Pow: 2.41

ENVIRONMENTAL
DATA

This substance may be hazardous to the environment; special attention should be given to water.

NOTES

Explosive limits are unknown in literature. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. The relation between odour and the occupational exposure limit cannot be indicated.

Transport Emergency Card: TEC (R)-879
NFPA Code: H 3; F 1; R 0;

IMPORTANT LEGAL NOTICE:

Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.