International Chemical Safety Cards DIALLYLAMINE ICSC: 0866 DIALLYLAMINE N-2-Propenyl-2-propen-1-amine di-2-propenylamine (CH2CHCH2)2NH/C6H11N Molecular mass: 97.16 CAS # 124-02-7 RTECS # UC6650000 ICSC # 0866 UN # 2359 TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames, NO sparks, and NO smoking. Powder, alcohol-resistant foam, water spray, carbon dioxide. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. In case of fire: keep drums, etc., cool by spraying with water.   EXPOSURE STRICT HYGIENE! INHALATION Burning sensation. Cough. Sore throat. Chest pain. Shortness of breath. Ventilation, local exhaust, or breathing protection. Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention. SKIN MAY BE ABSORBED! Redness. Pain. Blisters. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention. EYES Severe eye irritation. Redness. Pain. Tear drawing. Blurred vision. Face shield. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. INGESTION Burning sensation of the mouth, throat and digestive tract. Headache. Nausea. Weakness. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place (extra personal protection: complete protective clothing including self-contained breathing apparatus). Fireproof. Separated from strong oxidants, strong acids. UN Hazard Class: 3 UN Packing Group: II SEE IMPORTANT INFORMATION ON BACK ICSC: 0866 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

International Chemical Safety Cards DIALLYLAMINE ICSC: 0866 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour mixes well with air, explosive mixtures are easily formed. CHEMICAL DANGERS: The substance decomposes on heating or on burning producing toxic gases (nitrogen oxides). The substance is a medium strong base. Reacts voilently with oxidants and acids. Attacks copper, tin, aluminium and zinc. Solutions of diallylamine in water may attack glass. OCCUPATIONAL EXPOSURE LIMITS (OELs): TLV not established. PDK: 1 mg/m3 P (USSR 1987). ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour, through the skin, and by ingestion. INHALATION RISK: A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C, however much faster on spraying. EFFECTS OF SHORT-TERM EXPOSURE: Corrosive. The substance is very corrosive to the eyes, the skin and the respiratory tract. Inhalation of the vapour may cause lung oedema (see Notes). Inhalation of the vapour may cause effects on the heart. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 111°C Melting point: -88°C Relative density (water = 1): 0.8 Solubility in water, g/100 ml: 8.6 Solubility in water: Moderate (8.6/100 ml at 25°C) Vapour pressure, kPa at 20°C: 2.4 Relative vapour density (air = 1): 3.4 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06 Flash point: 15°C

ENVIRONMENTAL DATA
NOTES
Explosive limits are unknown in literature. Diallylamine can react with nitrating agents to form carcinogenic nitrosamines. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered. The relation between odour and the occupational exposure limit cannot be indicated. Transport Emergency Card: TEC (R)-30G31

ADDITIONAL INFORMATION
ICSC: 0866 DIALLYLAMINE © IPCS, CEC, 1993

IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.